You got to use the Exchange Management Shell to move the database path and log folder path in Exchange 2013
You will be using Move-Databasepath Cmdlet
Move-Databasepath DatabaseName EdbFilepath C:\NewlocationDBname.edb LogFolderpath C:\Newlocation
Caution ** It will dismount the stores temporarily which will cause you downtime.
How to Verify it has been moved Successfully
You can Run
Get-MailboxDatabase DatabaseName | FL Name,*Path*
or
You can login to Exchange Admin Center
You can see the New Database Path
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